The international fertiliser society proceedings pp. It is intended to create an environmental condition of reproducible severity. Ammonia stress corrosion cracking can also affect carbon steel equipment, but unlike the cracking mechanism on brass which occurs in an aqueous solution, the cracking of steel equipment occurs in anhydrous ammonia. Stresscorrosion cracking has been determined as the cause of failure of carbon steel tanks in agricultural ammonia service. Examples of catastrophic failure of nh3 refrigeration vessels caused. There are several important environmentsalloy combinations that are frequent problems for scc in cooling water systems, including. A stainless steel seems like a better choice for this application. Stresscorrosion cracking of steel occurs in the coc02h20 system when these three environmental components are present together.
For example, stainless steel is extremely susceptible to stress corrosion cracking in the presence of chlorides. Water in ammonia to protect against stress corrosion. Stress corrosion cracking of welded carbon steel in liquid ammonia was studied with bend specimens made from carbon steel plates welded with different welding electrodes. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Ammonia at normal atmospheric temperatures and pressures is a gas. The harmful effect of grinding upon the resistance of steel to stresscorrosion cracking, very much in evidence in specimens with a martensitic structure, is negligible in the. Water in ammonia to protect against stress corrosion cracking.
Ammonia corrosion can cause stress corrosion cracking in steels. Stress corrosion crack growth of carbon steel in ammonia was studied with. A laboratory study on metal corrosion by ammonia gas. Stress corrosion cracking in carbon steel dear all, we are inspecting a ammonia storage tank which was in service for more than 30 years. Temperature and corrosion rate more complex than you think. Other terms for caustic scc used in past literature include caustic embrittlement, caustic cracking, and alkaline cracking. Weight losses for uncoated 1010 carbon steel samples in the chamber without ammonia were three and six times higher than those in chambers with ammonia levels of 100 ppm and 200 ppm, respectively. Also the return of empty transport tanks can be a source of oxygen.
On discovery of a source of moist ammonia in the system, associated with the location of failure, intergranular stresscorrosion cracking scc was identified as the failure mechanism. Cases of stress corrosion cracking scc in steel vessels using nh3 have been reported by members of the ammonia refrigeration industry. Ammonia stress corrosion cracking can also affect carbon steel equipment, but unlike the. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack growth rates associated with stress corrosion to.
Prevention of stress corrosion cracking of carbon steels. Within the iso committee tc 26sc 2, wrought copper and copper alloys, a working group, wg4, has been set up to propose an ammonia test to evaluate the. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Ammonia test for stress corrosion resistance of copper alloys. It can be stored under pressure as a liquid or below its atmospheric boiling point of 34 degc. Evaluation of ammonia hydroxide for mitigating stress. Selection of stainless steels for handling ammonia nh3. Effects of ammonia contaminants, such as air, water, carbon dioxide, oil, etc on failure rates were studied. Used only where there are no actual data to estimate the risk of localised corrosion instead of p or s. Stress corrosion cracking of carbon steel storage tanks. Copper alloys can be attacked by carbon dioxide depending on what oxidants, including dissolved oxygen, are present. Thus, the addition of caustic soda to boiler feed waters to reduce the corrosiveness of the latter towards mild steel can result in the form of stress corrosion frequently referred to as caustic cracking.
These cracks are not visible initially, but as time passes, these individual cracks may grow and forms colonies, and many of them join together to form longer cracks. Review papers on condensation corrosion in dead legs. This condition generally requires a service temperature above 120 degrees 49c and general corrosion is very unlikely unless unusual contaminants are. Stress corrosion cracking in the ammonia refrigeration. Stress corrosion cracking of steel in liquefied ammonia.
Unlike the cracking mechanism on brass, which occurs in an aqueous solution, the cracking of steel equipment occurs in anhydrous ammonia just the opposite. There are specific stresscracking agents for brasses, these are usually ammonia or its derivatives. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Copper alloys can also suffer stress corrosion cracking and other forms of attack in ammonia service. Pdf mechanical integrity and carbon steel refrigerant piping. Astm b858 062018 standard test method for ammonia vapor. Permanent joints of pipes produced by hardsoldering of aluminiumaluminium and aluminiumaustenitic cr ni steels are mechanically solid and corrosionresistant. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Oxygen levels of more than a few ppm in liquid ammonia or a few thousand ppm in gaseous ammonia can promote stress corrosion cracking in steels.
For brasses the environment involved is usually one containing ammonia or closely related substances such as amines, but atmospheres containing between 0. On discovery of a source of moist ammonia in the system, associated with the location of failure, intergranular stress corrosion cracking scc was identified as the failure mechanism. Stress corrosion cracking in refrigeration systems request pdf. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Stress corrosion cracking of steel in liquefied ammonia service a recapitulation. Three electrodes commonly used for construction of ammonia storage tanks and one recently developed low strength electrode were studied at ambient temperature. A study was made to determine relevant growth data and to determine methods to prevent cracking. Four factors, are required before stress corrosion cracking can occur. Stress corrosion cracking international institute of. The cupric ion present in the solution appears as an oxidant that provides a cathodic reaction and induces stress corrosion cracking of brass in ammonia and ammoniacal solutions. Ammonia and stainless steel, corrosion blacksmith37 materials dec 11 10. Carbon steel in anhydrous ammonia can suffer from scc stress corrosion cracking.
If moisture is present in an alkaline environment it may absorb ammonia and such solutions, in conjunction with residual stress, can initiate stress corrosion cracking. Stress corrosion cracking scc of the welds in carbon steel transport and storage tanks for anhydrous ammonia has been experienced worldwide for the last 30 years. Stainless steels in ammonia production nickel institute. Another form of ammonia scc afflicts carbon steel equipment. The committee determined that the failures were most likely caused by stresscorrosion cracking and that the probability of cracking increased as the yield strength of the steel increased. Stress corrosion cracking of carbon steel storage tanks for. Moustafa said seleet a dissertation submitted to the graduate faculty in partial fulfillment of the.
Corrosion is related to the susceptibility of the material to the environment, while stresses may be residual, external or. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of stress corrosion can be prevented are ignored. What causes stress corrosion cracking in pipelines. Pugh, the theory of stress corrosion cracking in alloys j.
The carbon steel casings of heat recovery steam generators hrsgs in a cogeneration plant were found to have developed cracks that originated on the inside surfaces. This paper reports the work conducted to evaluate nh4oh as an inhibitor to mitigate scc of carbon steel in simulated fge sfge. Corrosion in cold insulated systems insulation outlook. Some proprietary caustic solutions are used in the industry, e. Typically the indication of a leak due to stress corrosion cracking is a strong smell of ammonia gas seeping through a short hairline crack on a pressure vessel. Temperature and corrosion rate more complex than you. Jul 11, 2011 the committee determined that the failures were most likely caused by stress corrosion cracking and that the probability of cracking increased as the yield strength of the steel increased. Stresscorrosion cracking of steels in ammonia with.
It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of. Even in these situations, the corrosion rate increase with temperature may vary from 1. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stresscorrosion cracking scc in aircontaminated dry ammonia. The aluminium alloys intended for use in ammonia cycles are not affected by stress corrosion cracking. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. First, the part must be stressed, either from an applied force or due to residual stress usually from forming.
Avoiding caustic stress corrosion cracking of refinery equipment. Stress corrosion cracking in pipelines begins when small cracks develop on the external surface of buried pipelines. The highest susceptibility to scc was found in liquid ammonia with 3 to 10 ppm oxygen and a water content lower than 100 ppm. Mechanical integrity and carbon steel refrigerant piping. Stress corrosion cracking in refrigeration systems. Care must be taken to ensure that pressure vessels are not subjected to this type of corrosion. Anhydrous ammonia in carbon steels and quenchedandtempered lowalloy steels in the presence of air in addition to stress, oxygen is a critical ingredient to enable scc nitrogen aggravates the process source. This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Electrochemistry of stress corrosion cracking of brass.
Under more severe conditions, when there is also a risk of pitting corrosion, the symbols p or p are used instead. Austenitic stainless steel pipe and equipment is unlikely to develop stress corrosion cracking scc, provided the metals temperature is kept cool. It has been found that scc in fge can be inhibited by adding inhibitors. Systems with airoxygen contamination also tend to be particularly vulnerable to this issue. Stress corrosion cracking in a brewery paul mueller company. The dissolved carbon monoxide in the water forms an inhibitive layer on the surface of the steel. The hrsgs receive hot exhaust gases from the primary gas turbines gts, which are fuelled with pipeline natural gas. Stress corrosion cracking of different steels in liquid. Stress corrosion cracking of steel in liquefied ammonia service a.
Stresscorrosion cracking of steel in liquefied ammonia is traced from its early. Stress corrosion cracking of carbon steel springerlink. Carbon steel is susceptible to stress corrosion cracking scc in fuel grade ethanol fge. A modified design, incorporating annealing of the formed copper tube section, was recommended to avoid future failures. While it is rare, formed parts can develop fractures after they are placed in service. In general, air contamination increased stresscorrosion cracking and water in small amounts inhibited the attack. Stress corrosion cracking of carbon steel storage tanks for anhydrous ammonia. Increasing the plasticity of the steel causes a reduction in its proneness to stresscorrosion cracking, which does not occur at all in specimens tempered at 550c. Stress corrosion cracking scc corrosion and failure. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. The unsolved problems 23 experimental 27 material 27 stress corrosion cracking samples 27 electrochemical tests samples 27 solutions 28 measurement techniques 29. Stress corrosion cracking scc in boilers and cooling water.
Stress corrosion cracking or season cracking occurs only in the simultaneous presence of a sufficiently high tensile stress and a specific corrosive environment. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes. The important general point is that those environments that cause stress corrosion are frequently highly specific to the particular. Stresscorrosion cracking of steels in agricultural ammonia. Stress corrosion cracking scc in boilers and cooling. Carbon and lowalloy steels scc can occur in other materials stainless steel. The cracks are small at the surface but can be deep, worstcase going through the entire thickness of the metal. Stress corrosion cracking scc is a type of environmentallyassisted cracking eac, or the formation of cracks caused by various factors combined with the environment surrounding the pipeline. Using other materials, such as stainless steel or copper, introduces a whole new set of failure mechanisms. The main issue is the cryogenic toughness of stainless steels at around 40 degc, compared to carbon steels, which can also be considered for ammonia service under these conditions. Electrochemistry of stress corrosion cracking of brass by m. The test results showed that aerial ammonia, instead of accelerating metal corrosion, reduced the corrosion rates for steel. Ineffective refrigeration due to excess oil within the system, causing the system to work harder than necessary, thus stressing the system components.
But if the corrosion rate is controlled by other factors, such as the presence of oxygen in the corrosive. A modified design, incorporating annealing of the formed copper tube section, was recommended to. There are three factors under which stress corrosion cracking is possible a corrosive mediumenvironment b material and c tensile stress. Consider using diaphragm seals for liquid level measurement. There are no known fatalities due to stress corrosion cracking in ammonia refrigeration vessels, and no reported cases of vessels rupturing or fracturing in service. When migrating the old forums over to our new forums we were unable to retain the identity of the authors, so the old posts will show up as anonymous.
This type of failure is referred to as stress corrosion cracking scc. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in contaminated cooling water service. Request pdf stress corrosion cracking in refrigeration systems it is generally. The scc of carbon and alloy steels in ammonia service has occurred. Prevention of stress corrosion cracking of carbon steels in. Stress corrosion cracking in ammonia did not occur in steel specimens with fatigue precracks, due to a crevice corrosion attack. Stresscorrosion cracking in copper refrigerant tubing. Stresscorrosion cracking of steel in liquefied ammonia is traced from its early recognition in the 1950s, from experiences in agricultural and industrial use from nace national association of corrosion engineers recommended dot department of transportation regulations to prevent damage, and from laboratory studies to explain the factors involved. Scc occurs as a result of a combination between corrosion and tensile stress. For example, stainless steel is extremely susceptible to stress corrosion cracking in the presence of. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented.
Ammonia stress corrosion cracking a mmonia stress corrosion cracking scc is the phenomena of cracks being formed in carbon steel in contact with ammonia. Stress corrosion cracking of brass in nonammoniacal solutions 15 stress corrosion cracking of pure copper 21 summary of stress corrosion cracking studies. Mixing copper with other metal result in excellent copper. It is very difficult to determine the total stress in a vessel during auto. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. This occurs when contaminants in the ammonia are brought into contact with the steel, a situation that commonly occurs with pressure vessels. There are specific stress cracking agents for brasses, these are usually ammonia or its derivatives. The combined effect of water and oxygen on stress corrosion cracking scc of carbon manganese steel in liquid and vaporous ammonia has been studied in detail. Regularly inspect the carbon steel bridle chamber installed until the next turnaround cycle. Nitrate stress corrosion cracking of carbon steel equipment. Stress corrosion cracking scc in cooling water systems.
1211 191 72 1187 1509 156 1246 174 71 527 1134 1117 1531 621 1581 627 1288 647 65 1240 766 932 1471 405 809 634 187 339 317 788